Issue 21, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

Martin Banwell,*a   David Hockless,a   Bevyn Jarrott,b   Brian Kelly,a   Andrew Knill,bc   Robert Longmorea  and  Gregory Simpsonc  

* Corresponding authors

a Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, Australia

b Department of Pharmacology, Monash University, Wellington Road, Clayton, Victoria, Australia

c CSIRO Molecular Science, Bag 10, Clayton South, Victoria, Australia

Abstract

The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels–Alder cycloaddition reactions with maleic and citraconic anhydride to give adducts (e.g.25–27) embodying the ABC-ring system associated with spinosyns A (1) and D (2).

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Article information

DOI
https://doi.org/10.1039/B006759H
Article type
Communication
Submitted
17 Aug 2000
Accepted
21 Sep 2000
First published
12 Oct 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 3555-3558

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Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

M. Banwell, D. Hockless, B. Jarrott, B. Kelly, A. Knill, R. Longmore and G. Simpson, J. Chem. Soc., Perkin Trans. 1, 2000, 3555 DOI: 10.1039/B006759H

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