Diethyl diethylmalonate: Difference between revisions

Diethyl diethylmalonate
	File:Diethyldiethylmalonate.png
Names
	IUPAC name diethyl 2,2-diethylpropanedioate
	Other names Diethyl diethylmalonate; Diethyl 2,2-diethylmalonate; .
Identifiers
CAS Number	77-25-8 ;
3D model (JSmol)	Interactive image;
ChemSpider	21159400;
ECHA InfoCard	100.000.925
EC Number	201-016-2;
PubChem CID	66165;
UNII	CEH13944YQ;
CompTox Dashboard (EPA)	DTXSID0058807 ;
	InChI InChI=1S/C11H20O4/c1-5-11(6-2,9(12)14-7-3)10(13)15-8-4/h5-8H2,1-4H3 Key: ZKBBUZRGPULIRN-UHFFFAOYSA-N; InChI=1S/C11H20O4/c1-5-11(6-2,9(12)14-7-3)10(13)15-8-4/h5-8H2,1-4H3;
	SMILES CCC(CC)(C(=O)OCC)C(=O)OCC;
Properties
Chemical formula	C11H20O4
Molar mass	216.27 g/mol
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

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Revision as of 21:23, 27 January 2024

Diethyl diethyl malonate or diethyl 2,2-diethylmalonate is a derivative of Diethyl Malonate. It can be used in the synthesis of Barbital^[2]

Uses

As being a diethyl malonate derivative, it can be combined with Urea under the action of a strong base to form a Barbiturate. In this case, diethyl diethyl malonate + urea forms barbital under the action of sodium ethoxide.

References

^ "Diethyl diethylmalonate". pubchem.ncbi.nlm.nih.gov.
^ "Synthesis of Barbiturates". www.erowid.org.

This organic chemistry article is a stub. You can help Wikipedia by expanding it.

[1] "Diethyl diethylmalonate". pubchem.ncbi.nlm.nih.gov.

[2] "Synthesis of Barbiturates". www.erowid.org.

[1]

[2]

@@ Line 13: / Line 13: @@
 | Section1       = {{Chembox Identifiers
 | CASNo          = 77-25-8
+| CASNo_Ref = {{Cascite|correct|CAS}}
+| ChemSpiderID = 21159400
+| EC_number = 201-016-2
 | InChI          = 1S/C11H20O4/c1-5-11(6-2,9(12)14-7-3)10(13)15-8-4/h5-8H2,1-4H3
 | PubChem        = 66165
+| UNII = CEH13944YQ
+| StdInChI=1S/C11H20O4/c1-5-11(6-2,9(12)14-7-3)10(13)15-8-4/h5-8H2,1-4H3
+| StdInChIKey = ZKBBUZRGPULIRN-UHFFFAOYSA-N
 | SMILES         = CCC(CC)(C(=O)OCC)C(=O)OCC
   }}
@@ Line 32: / Line 38: @@
   }}
 }}
-'''Diethyl diethyl malonate''' or '''Diethyl 2,2-diethylmalonate''' is a derivative of [[Diethyl malonate|Diethyl Malonate]].
+'''Diethyl diethyl malonate''' or '''diethyl 2,2-diethylmalonate''' is a derivative of [[diethyl malonate|Diethyl Malonate]].
 It can be used in the synthesis of [[Barbital]]<ref>{{Cite web|url=https://www.erowid.org/archive/rhodium/chemistry/barbiturates.html|title=Synthesis of Barbiturates|website=www.erowid.org}}</ref>
 == Uses ==
-As being a [[Diethyl malonate|Diethyl Malonate]] derivative, it can be combined with [[Urea]] under the action of a strong base to form a [[Barbiturate]]. In this case, Diethyl diethyl malonate + [[Urea]] forms [[Barbital]] under the action of [[sodium ethoxide|Sodium ethoxide]].
+As being a [[diethyl malonate]] derivative, it can be combined with [[Urea]] under the action of a strong base to form a [[Barbiturate]]. In this case, diethyl diethyl malonate + [[urea]] forms [[barbital]] under the action of [[sodium ethoxide]].
 :[[Image:Barbital Synthese.svg|390px]]