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=== Greenland ===
=== Greenland ===
==== Dye 3 ====


The first to winter on the inland ice was J.P. Koch and Alfred Wegener in a hut they built on the ice in Northeast Greenland.<ref name=Dansgaard>{{ cite book |author=Dansgaard W |title=Frozen Annals Greenland Ice Sheet Research |isbn=87-990078-0-0 |publisher=Narayana Press |location=Odder, Denmark |pages=124 }}</ref> Inside the hut they drilled to a depth of 25 m with an auger similar to an oversized corkscrew.

====Station [[Eismitte]]====
{{main|Eismitte}}

Eismitte means Ice-Center in German, and the campsite was located 402 kilometers (250 miles) from the coast at an estimated altitude of 3,000 meters (9,843 feet).

As a member of the Alfred Wegener Expedition to Eismitte in central Greenland from July 1930 to August 1931, Ernst Sorge hand-dug a 15 m deep pit adjacent to his beneath-the-surface snow cave. Sorge was the first to systematically and quantitatively study the near-surface snow/firn strata from inside his pit. His research validated the feasibility of measuring the preserved annual snow accumulation cycles, like measuring frozen precipitation in a rain gauge.<ref name=Langway>{{ cite web |author=Langway CC Jr. |title=The History of Early Polar Ice Cores |url=http://www.nicl-smo.sr.unh.edu/Langway_2008_Early_polar_ice_cores.pdf |month=Jan |year=2008 }}</ref>

====Camp VI====

During 1950-1951 members of Expeditions Polaires Francaises (EPF) led by Paul Emile Victor reported boring two holes to depths of 126 and 150 m on the central Greenland inland ice at Camp VI and Station Central (Centrale).<ref name=Wegener>{{ cite journal |author=Wegener K |title=Die temperatur in Grönlandischen inlandeis |journal=Pure Appl Geophys. |month=Sep |year=1955 |volume=32 |issue=1 |pages=102-6 |doi=10.1007/BF01993599 }}</ref> Camp VI is in the western part of Greenland on the EPF-EGIG line at an elevation of 1598 masl.

====Station Central====

The Station Centrale was not far from station Eismitte.<ref name=Dansgaard>{{ cite book |author=Dansgaard W |title=Frozen Annals Greenland Ice Sheet Research |isbn=87-990078-0-0 |publisher=Narayana Press |location=Odder, Denmark |pages=124 }}</ref> Centrale is on a line between Milcent (70°18’N 45°35’W, 2410 masl) and Crête (71°7’N 37°19’W), at about (70°43'N 41°26'W), whereas Eismitte is at (71°10’N 39°56’W, ~3000 masl).

====Site 2====

In 1956, pre-International Geophysical Year (IGY) of 1957-58, a 10 cm diameter core using a rotary mechanical drill (US) to 305 m was recovered.<ref name=Langway>{{ cite web |author=Langway CC Jr. |title=The History of Early Polar Ice Cores |url=Langway_2008_Early_polar_ice_cores.pdf |month=Jan |year=2008 }}</ref>

A second 10 cm diameter core was recovered in 1957 by the same drill rig to 411 m. A commercially modified, mechanical-rotary Failing-1500 rock-coring rig was used, fitted with special ice cutting bits.<ref name=Langway/>

====Camp Century====

Three cores were attempted at Camp Century in 1961, 1962, and again in 1963. The third hole was started in 1963 and reached 264 m. The 1963 hole was re-entered using the thermal drill (US) in 1964 and extended to 535 m. In mid-1965 the thermal drill was replaced with an electro-mechanical drill, 9.1 cm diameter, that reached the base of the ice sheet in July 1966 at 1387 m. The Camp Century, Greenland, (77°10’N 61°8’W, 1885 masl) ice core (cored from 1963-1966) is 1390 m deep and contains climatic oscillations with periods of 120, 940, and 13,000 years.<ref name=Dansgaard>{{ cite journal |author=Dansgaard W, Johnsen SJ, Møller J, Langway Jr CC |title=One Thousand Centuries of Climatic Record from Camp Century on the Greenland Ice Sheet |journal=Science. |volume=166 |issue=3903 |month=Oct |year=1969 |pages=377-80 |doi=10.1126/science.166.3903.377 }}</ref>

Another core in 1977 was drilled at Camp Century using a Shallow (Dane) drill type, 7.6 cm diameter, to 100 m.

====North Site====

At the North Site (75°46’N 42°27’W, 2870 masl) drilling began in 1972 using a SIPRE (US) drill type, 7.6 cm diameter to 25 m. The North Site was 500 km north of the EGIG line. At a depth of 6-7 m diffusion had obliterated some of the seasonal cycles.<ref name=Dansgaard>{{ cite book |author=Dansgaard W |title=Frozen Annals Greenland Ice Sheet Research |isbn=87-990078-0-0 |publisher=Narayana Press |location=Odder, Denmark |pages=124 }}</ref>

====North Central====

The first core at North Central (74°37’N 39°36’W) was drilled in 1972 using a Shallow (Dane) drill type, 7.6 cm diameter to 100 m.

====Crête====

At Crête in central Greenland (71°7’N 37°19’W) drilling began in 1972 on the first core using a SIPRE (US) drill type, 7.6 cm diameter to 15 m.

The Crête core was drilled in central Greenland (1974) and reached a depth of 404.64 meters, extending back only about fifteen centuries.<ref name=Rose2>{{ cite journal |author=Rose LE |title=The Greenland Ice Cores |journal=Kronos |month=Winter |volume=12 |issue=1 |pages=55-68 }}</ref> Annual cycle counting showed that the oldest layer was deposited in 534 AD.<ref name=Dansgaard>{{ cite book |author=Dansgaard W |title=Frozen Annals Greenland Ice Sheet Research |isbn=87-990078-0-0 |publisher=Narayana Press |location=Odder, Denmark |pages=124 }}</ref>

The Crête 1984 ice cores consist of 8 short cores drilled in the 1984-85 field season as part of the post-GISP campaigns. Glaciological investigations were carried out in the field at eight core sites (A-H).<ref name=creteNOAA>{{ cite web |title=Crete Ice Core |url=http://www.ncdc.noaa.gov/paleo/icecore/greenland/gisp/crete/crete.html }}</ref>

====Milcent====

"The first core drilled at Station Milcent in central Greenland covers the past 780 years."<ref name=Oeschger>{{ cite journal |author=Oeschger H, Beer J, Andree M |title=<sup>10</sup>Be and <sup>14</sup>C in the Earth system |journal=Phil Trans R Soc Lond A. |month=Aug |year=1987 |volume=323 |issue=1569 |pages=45-56 }}</ref> Milcent core was drilled at 70.3°N, 44.6°W, 2410 masl.<ref name=Oeschger/> The Milcent core (398 m) was 12.4 cm in diameter, using a Thermal (US) drill type, in 1973.

====Dye 2====

Drilling with a Shallow (Swiss) drill type at Dye 2 (66°23’N 46°11’W, 2338 masl) began in 1973. The core was 7.6 cm in diameter to a depth of 50 m. A second core to 101 m was 10.2 cm in diameter was drilled in 1974. An additional core at Dye 2 was drilled in 1977 using a Shallow (US) drill type, 7.6 cm diameter, to 84 m.

====Summit====

The camp is located approximately 360 km from the east coast and 500 km from the west coast of Greenland at (Saattut, Uummannaq), and 200 km NNE of the historical ice sheet camp Eismitte. The closest town is Ittoqqortoormiit, 460 km ESE of the station. The station however is not part of Sermersooq municipality, but falls within the bounds of the Northeast Greenland National Park.

An initial core at [[Summit Camp|Summit]] (71°17’N 37°56’W, 3212 masl) using a Shallow (Swiss) drill type was 7.6 cm in diameter for 31 m in 1974. Summit Camp, also Summit Station, is a year-round research station on the apex of the Greenland Ice Sheet. Its coordinates are variable, since the ice is moving. The coordinates provided here (72°34’45”N 38°27’26”W, 3212 masl) are as of 2006.

====South Dome====

The first core at South Dome (63°33’N 44°36’W, 2850 masl) used a Shallow (Swiss) drill type for a 7.6 cm diameter core to 80 m in 1975.

====Hans Tausen (or Hans Tavsen)====

The first GISP core drilled at Hans Tausen (82°30’N 38°20’W, 1270 masl) was in 1975 using a Shallow (Swiss) drill type, 7.6 cm diameter core to 60 m. The second core at Hans Tausen was drilled in 1976 using a Shallow (Dane) drill type, 7.6 cm diameter to 50 m. The drilling team reported that the drill was stuck in the drill hole and lost.

The Hans Tausen ice cap in Peary Land was drilled again with a new deep drill to 325 m. The ice core contained distinct melt layers all the way to bedrock indicating that Hans Tausen contains no ice from the glaciation; i.e., the world’s northernmost ice cap melted away during the post-glacial climatic optimum and was rebuilt when the climate got colder some 4000 years ago.<ref name=Dansgaard>{{ cite book |author=Dansgaard W |title=Frozen Annals Greenland Ice Sheet Research |isbn=87-990078-0-0 |publisher=Narayana Press |location=Odder, Denmark |pages=124 }}</ref>

====Camp III====

The first core at Camp III (69°43’N 50°8’W) was drilled in 1977 using a Shallow (Swiss) drill type, 7.6 cm, to 49 m. The last core at Camp III was drilled in 1978 using a Shallow (Swiss) drill type, 7.6 cm diameter, 80 m depth.

==== Dye 3 ====
{{main|Dye 3}}
{{main|Dye 3}}

The Greenland Ice Sheet Project (GISP) including Dye 3 was a decade-long project to drill 20<ref name=ncdc>{{ cite web |title=NOAA Paleoclimatology World Data Centers Dye 3 Ice Core |url=http://www.ncdc.noaa.gov/paleo/icecore/greenland/gisp/dye3/dye3.html }}</ref> [[ice core]]s in [[Greenland]].

====Renland====

The Renland ice core was drilled in 1985.<ref name=Dansgaard>{{ cite book |author=Dansgaard W |title=Frozen Annals Greenland Ice Sheet Research |isbn=87-990078-0-0 |publisher=Narayana Press |location=Odder, Denmark |pages=124 }}</ref> The Renland ice core from East Greenland apparently covers a full glacial cycle from the Holocene into the previous Eemian interglacial. The Renland ice core is 325 m long.<ref name=Hansson1>{{ cite journal |author=Hansson M, Holmén K |title= |journal=Geophy Res Lett. |month=Nov |year=2001 |volume=28 |issue=22 |pages=4239-42 |doi=10.1029/2000GL012317 }}</ref>

From the delta-profile, the Renland ice cap in the Scoresbysund Fiord has always been separated from the inland ice, yet all the delta-leaps revealed in the Camp Century 1963 core recurred in the Renland ice core.<ref name=Dansgaard>{{ cite book |author=Dansgaard W |title=Frozen Annals Greenland Ice Sheet Research |isbn=87-990078-0-0 |publisher=Narayana Press |location=Odder, Denmark |pages=124 }}</ref>


==== GRIP/GISP ====
==== GRIP/GISP ====
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The NGRIP drilling site is near the center of [[Greenland]] ({{coord|75.1|N|42.32|W|type:landmark|name=NGRIP drilling site}}, 2917 m, ice thickness 3085). Drilling began in 1999 and was completed at bedrock in 2003.{{ref|news.bbc.co.uk.888}} The NGRIP site was chosen to extract a long and undisturbed record stretching into the last glacial. NGRIP covers 5 kyr of the [[Eemian Stage|Eemian]], and shows that temperatures then were roughly as stable as the pre-industrial [[Holocene]] temperatures were.
The NGRIP drilling site is near the center of [[Greenland]] ({{coord|75.1|N|42.32|W|type:landmark|name=NGRIP drilling site}}, 2917 m, ice thickness 3085). Drilling began in 1999 and was completed at bedrock in 2003.{{ref|news.bbc.co.uk.888}} The NGRIP site was chosen to extract a long and undisturbed record stretching into the last glacial. NGRIP covers 5 kyr of the [[Eemian Stage|Eemian]], and shows that temperatures then were roughly as stable as the pre-industrial [[Holocene]] temperatures were.

====[[NEEM]]====

The North Greenland Eemian Ice Drilling (NEEM) site is located at 77°27’N 51°3.6’W, masl. Drilling started in June 2009 and expects to hit bedrock in 2010. The ice at NEEM may be 2545 m thick. As of Sep 1, 2009, the coring has reached a 1757.84 m depth for this season.


=== Antarctica ===
=== Antarctica ===

Revision as of 23:19, 5 September 2009

Ice Core sample taken from drill. Photo by Lonnie Thompson, Byrd Polar Research Center.

An ice core is a core sample from the accumulation of snow and ice over many years that have re-crystallized and have trapped air bubbles from previous time periods. The composition of these ice cores, especially the presence of hydrogen and oxygen isotopes, provides a picture of the climate at the time.

Because water molecules containing heavier isotopes exhibit a lower vapor pressure, when the temperature falls, the heavier water molecules will condense faster than the normal water molecules. The relative concentrations of the heavier isotopes in the condensate indicate the temperature of condensation at the time, allowing for ice cores to be used in local temperature reconstruction after certain assumptions. In addition to the isotope concentration, the air bubbles trapped in the ice cores allow for measurement of the atmospheric concentrations of trace gases, including greenhouse gases carbon dioxide, methane, and nitrous oxide.

Ice cores contain an abundance of climate information. Inclusions in the snow of each year remain in the ice, such as wind-blown dust, ash, bubbles of atmospheric gas and radioactive substances. The variety of climatic proxies is greater than in any other natural recorder of climate, such as tree rings or sediment layers. These include (proxies for) temperature, ocean volume, precipitation, chemistry and gas composition of the lower atmosphere, volcanic eruptions, solar variability, sea-surface productivity, desert extent and forest fires.

Typical ice cores are removed from an ice sheet, most commonly from the polar ice caps of Antarctica, Greenland or from high mountain glaciers elsewhere. As the ice forms from the incremental buildup of annual layers of snow, lower layers are older than upper, and an ice core contains ice formed over a range of years. The properties of the ice or inclusions within the ice can then be used to reconstruct a climatic record over the age range of the core.

The length of the record depends on the depth of the ice core and varies from a few years up to 800 kyr for the EPICA core. The time resolution (i.e. the shortest time period which can be accurately distinguished) depends on the amount of annual snowfall, and reduces with depth as the ice compacts under the weight of layers accumulating on top of it. Upper layers of ice in a core correspond to a single year or sometimes a single season. Deeper into the ice the layers thin and annual layers become indistinguishable.

An ice core from the right site can be used to reconstruct an uninterrupted and detailed climate record extending over hundreds of thousands of years, providing information on a wide variety of aspects of climate at each point in time. It is the simultaneity of these properties recorded in the ice that makes ice cores such a powerful tool in paleoclimate research.

Structure of ice sheets and cores

Sampling the surface of Taku Glacier in Alaska. There is increasingly denser firn between surface snow and blue glacier ice.

Most ice sheets are formed from snow. Because an ice sheet survives summer, the temperature in that location usually does not warm much above freezing. In many locations in Antarctica the air temperature is always well below the freezing point of water. If the summer temperatures do get above freezing, any ice core record will be severely degraded or completely useless, since meltwater will percolate into the snow.

The surface layer is snow in various forms, with air gaps between snowflakes. As snow continues to accumulate, the buried snow is compressed and forms firn, a grainy material with a texture similar to granulated sugar. Air gaps remain, and some circulation of air continues. As snow accumulates above, the firn continues to densify, and at some point the pores close off and the air is trapped. Because the air continues to circulate until then, the ice age and the age of the gas enclosed are not the same, and may differ by hundreds of years. The gas age–ice age difference is as great as 7 kyr in glacial ice from Vostok.[1]

Under increasing pressure, at some depth the firn is compressed into ice. This depth may range between a few to several tens of meters to typically 100 m for Antarctic cores. Below this level material is frozen in the ice. Ice may appear clear or blue.

Layers can be visually distinguished in firn and in ice to significant depths. In a location on the summit of an ice sheet where there is little flow, accumulation tends to move down and away, creating layers with minimal disturbance. In a location where underlying ice is flowing, deeper layers may have increasingly different characteristics and distortion. Drill cores near bedrock often are challenging to analyze due to distorted flow patterns and composition likely to include materials from the underlying surface.

GISP2 ice core at 1837 meters depth with clearly visible annual layers.

Characteristics of firn

The layer of porous firn on Antarctic ice sheets is 50-150 m deep.[1] It is much less deep on glaciers.

Air in the atmosphere and firn are slowly exchanged by molecular diffusion through pore spaces, because gases move toward regions of lower concentration. Thermal diffusion causes isotope fractionation in firn when there is rapid temperature variation, creating isotope differences which are captured in bubbles when ice is created at the base of firn. There is gas movement due to diffusion in firn, but not convection except very near the surface.

Below the firn is a zone in which seasonal layers alternately have open and closed porosity. These layers are sealed with respect to diffusion. Gas ages increase rapidly with depth in these layers. Various gases are fractionated while bubbles are trapped where firn is converted to ice.[2]

Coring

A core is collected by separating it from the surrounding material. For material which is sufficiently soft, coring may be done with a hollow tube. Deep core drilling into hard ice, and perhaps underlying bedrock, involves using a hollow drill which actively cuts a cylindrical pathway downward around the core.

When a drill is used, the cutting apparatus is on the bottom end of a drill barrel, the tube which surrounds the core as the drill cuts downward around the edge of the cylindrical core. The length of the drill barrel determines the maximum length of a core sample (6 m at GISP2 and Vostok). Collection of a long core record thus requires many cycles of lowering a drill/barrel assembly, cutting a core 4-6 m in length, raising the assembly to the surface, emptying the core barrel, and preparing a drill/barrel for drilling.

Because deep ice is under pressure and can deform, for cores deeper than about 300 m the hole will tend to close if there is nothing to supply back pressure. The hole is filled with a fluid to keep the hole from closing. The fluid, or mixture of fluids, must simultaneously satisfy criteria for density, low viscosity, frost resistance, as well as workplace safety and environmental compliance. The fluid must also satisfy other criteria, for example those stemming from the analytical methods employed on the ice core. A number of different fluids and fluid combinations have been tried in the past. Since GISP2 (1990–1993) the US Polar Program has utilized a single-component fluid system, n-butyl acetate, but the toxicology, flammability, aggressive solvent nature, and longterm liabilities of n-butyl acetate raises serious questions about its continued application. The European community, including the Russian program, has concentrated on the use of two-component drilling fluid consisting of low-density hydrocarbon base (brown kerosene was used at Vostok) boosted to the density of ice by addition of halogenated-hydrocarbon densifier. Many of the proven densifier products are now considered too toxic, or are no longer available due to efforts to enforce the Montreal Protocol on ozone-depleting substances.[3] In April 1998 on the Devon Ice Cap filtered lamp oil was used as a drilling fluid. In the Devon core it was observed that below about 150 m the stratigraphy was obscured by microfractures.[4]

Core processing

Sawing the GRIP core

Modern practice is to ensure that cores remain uncontaminated, since they are analysed for trace quantities of chemicals and isotopes. They are sealed in plastic bags after drilling and analysed in clean rooms.

The core is carefully extruded from the barrel; often facilities are designed to accommodate the entire length of the core on a horizontal surface. Drilling fluid will be cleaned off before the core is cut into 1-2 meter sections. Various measurements may be taken during preliminary core processing.

Current practices to avoid contamination of ice include:

  • Keeping ice well below the freezing point.
    • At Greenland and Antarctic sites, temperature is maintained by having storage and work areas under the snow/ice surface.
    • At GISP2, cores were never allowed to rise above -15 °C, partly to prevent microcracks from forming and allowing present-day air to contaminate the fossil air trapped in the ice fabric, and partly to inhibit recrystallization of the ice structure.
  • Wearing special clean suits over cold weather clothing.
  • Mittens or gloves.
  • Filtered respirators.
  • Plastic bags, often polyethylene, around ice cores. Some drill barrels include a liner.
  • Proper cleaning of tools and laboratory equipment.
  • Use of laminar-flow bench to isolate core from room particulates.

For shipping, cores are packed in Styrofoam boxes protected by shock absorbing bubble-wrap.

Due to the many types of analysis done on core samples, sections of the core are scheduled for specific uses. After the core is ready for further analysis, each section is cut as required for tests. Some testing is done on site, other study will be done later, and a significant fraction of each core segment is reserved for archival storage for future needs.

Projects have used different core-processing strategies. Some projects have only done studies of physical properties in the field, while others have done significantly more study in the field. These differences are reflected in the core processing facilities.

Ice relaxation

Deep ice is under great pressure. When brought to the surface, there is a drastic change in pressure. Due to the internal pressure and varying composition, particularly bubbles, sometimes cores are very brittle and can break or shatter during handling. At Dome C, the first 1000 m were brittle ice. Siple dome encountered it from 400 to 1000 m. It has been found that allowing ice cores to rest for some time (sometimes for a year) makes them become much less brittle.

Decompression causes significant volume expansion (called relaxation) due to microcracking and the exsolving of enclathratized gases.[5] Relaxation may last for months.[6] During this time, ice cores are stored below -10 °C to prevent cracking due to expansion at higher temperatures. At drilling sites, a relaxation area is often built within existing ice at a depth which allows ice core storage at temperatures below -20 °C.

It has been observed that the internal structure of ice undergoes distinct changes during relaxation. Changes include much more pronounced cloudy bands and much higher density of "white patches" and bubbles.[7]

Several techniques have been examined. Cores obtained by hot water drilling at Siple Dome in 1997–1998 underwent appreciably more relaxation than cores obtained with the PICO electro-mechanical drill. In addition, the fact that cores were allowed to remain at the surface at elevated temperature for several days likely promoted the onset of rapid relaxation.[8]

Ice core data

Graph of CO2 (green), reconstructed temperature (blue) and dust (red) from the Vostok ice core for the past 420,000 years

Many materials can appear in an ice core. Layers can be measured in several ways to identify changes in composition. Small meteorites may be embedded in the ice. Volcanic eruptions leave identifiable ash layers. Dust in the core can be linked to increased desert area or wind speed.

Isotopic analysis of the ice in the core can be linked to temperature and global sea level variations. Analysis of the air contained in bubbles in the ice can reveal the palaeocomposition of the atmosphere, in particular CO2 variations. There are great problems relating the dating of the included bubbles to the dating of the ice, since the bubbles only slowly "close off" after the ice has been deposited. Nonetheless, recent work has tended to show that during deglaciations CO2 increases lags temperature increases by 600 +/- 400 years [9]. Beryllium-10 concentrations are linked to cosmic ray intensity which can be a proxy for solar strength.

There may be an association between atmospheric nitrates in ice and solar activity. However, recently it was discovered that sunlight triggers chemical changes within top levels of firn which significantly alter the pore air composition. This raises levels of formaldehyde and NOx. Although the remaining levels of nitrates may indeed be indicators of solar activity, there is ongoing investigation of resulting and related effects of effects upon ice core data.[10][11]

Core contamination

Some contamination has been detected in ice cores. The levels of lead on the outside of ice cores is much higher than on the inside.[12] In ice from the Vostok core (Antarctica), the outer portion of the cores have up to 3 and 2 orders of magnitude higher bacterial density and dissolved organic carbon than the inner portion of the cores, respectively, as a result of drilling and handling.[13]

Paleoatmospheric sampling

As porous snow consolidates into ice, the air within it is trapped in bubbles in the ice. This process continuously preserves samples of the atmosphere.[14] In order to retrieve these natural samples the ice is ground at low temperatures, allowing the trapped air to escape. It is then condensed for analysis by gas chromatography or mass spectrometry, revealing gas concentrations and their isotopic composition respectively. Apart from the intrinsic importance of knowing relative gas concentrations (e.g. to estimate the extent of greenhouse warming), their isotopic composition can provide information on the sources of gases. For example CO2 from fossil-fuel or biomass burning is relatively depleted in 13C. See Friedli et al., 1986.

Dating the air with respect to the ice it is trapped in is problematic. The consolidation of snow to ice necessary to trap the air takes place at depth (the 'trapping depth') once the pressure of overlying snow is great enough. Since air can freely diffuse from the overlying atmosphere throughout the upper unconsolidated layer (the 'firn'), trapped air is younger than the ice surrounding it.

Trapping depth varies with climatic conditions, so the air-ice age difference could vary between 2500 and 6000 years (Barnola et al., 1991). However, air from the overlying atmosphere may not mix uniformly throughout the firn (Battle et al., 1986) as earlier assumed, meaning estimates of the air-ice age difference could be less than imagined. Either way, this age difference is a critical uncertainty in dating ice-core air samples. In addition, gas movement would be different for various gases; for example, larger molecules would be unable to move at a different depth than smaller molecules so the ages of gases at a certain depth may be different. Some gases also have characteristics which affect their inclusion, such as helium not being trapped because it is soluble in ice.

In Law Dome ice cores, the trapping depth at DE08 was found to be 72 m where the age of the ice is 40±1 years; at DE08-2 to be 72 m depth and 40 years; and at DSS to be 66 m depth and 68 years.[15]

Paleoatmospheric firn studies

Ozone-depleting gases in Greenland firn.

At the South Pole, the firn-ice transition depth is at 122 m, with a CO2 age of about 100 years. Gases involved in ozone depletion, CFCs, chlorocarbons, and bromocarbons, were measured in firn and levels were almost zero at around 1880 except for CH3Br, which is known to have natural sources.[16] Similar study of Greenland firn found that CFCs vanished at a depth of 69 m (CO2 age of 1929).[17]

36Cl from 1960s nuclear bombs in US glacier ice.

Analysis of the Upper Fremont Glacier ice core showed large levels of chlorine-36 that definitely correspond to the production of that isotope during atmospheric testing of nuclear weapons. This result is interesting because the signal exists despite being on a glacier and undergoing the effects of thawing, refreezing, and associated meltwater percolation.[18] 36Cl has also been detected in the Dye-3 ice core (Greenland)[19], and in firn at Vostok.[20]

Studies of gases in firn often involve estimates of changes in gases due to physical processes such as diffusion. However, it has been noted that there also are populations of bacteria in surface snow and firn at the South Pole, although this study has been challenged.[21][22] It had previously been pointed out that anomalies in some trace gases may be explained as due to accumulation of in-situ metabolic trace gas byproducts.[23]

Dating cores

19 cm long section of GISP 2 ice core from 1855 m showing annual layer structure illuminated from below by a fiber optic source. Section contains 11 annual layers with summer layers (arrowed) sandwiched between darker winter layers.

Shallow cores, or the upper parts of cores in high-accumulation areas, can be dated exactly by counting individual layers, each representing a year. These layers may be visible, related to the nature of the ice; or they may be chemical, related to differential transport in different seasons; or they may be isotopic, reflecting the annual temperature signal (for example, snow from colder periods has less of the heavier isotopes of H and O). Deeper into the core the layers thin out due to ice flow and high pressure and eventually individual years cannot be distinguished. It may be possible to identify events such as nuclear bomb atmospheric testing's radioisotope layers in the upper levels, and ash layers corresponding to known volcanic eruptions. Volcanic eruptions may be detected by visible ash layers, acidic chemistry, or electrical resistance change. Some composition changes are detected by high-resolution scans of electrical resistance. Lower down the ages are reconstructed by modeling accumulation rate variations and ice flow.

Dating is a difficult task. Five different dating methods have been used for Vostok cores, with differences such as 300 years at 100 m depth, 600yr at 200 m, 7000yr at 400 m, 5000yr at 800 m, 6000yr at 1600 m, and 5000yr at 1934 m.[24]

Different dating methods makes comparison and interpretation difficult. Matching peaks by visual examination of Moulton and Vostok ice cores suggests a time difference of about 10,000 years but proper interpretation requires knowing the reasons for the differences.[25]

Ice core sites

Ice cores have been taken from many locations around the world. Major efforts have taken place on Greenland and Antarctica.

Sites on Greenland are more susceptible to snow melt than those in Antarctica. In the Antarctic, areas around the Antarctic Peninsula and seas to the west have been found to be affected by ENSO effects. Both of these characteristics have been used to study such variations over long spans of time.[26]

Greenland

The first to winter on the inland ice was J.P. Koch and Alfred Wegener in a hut they built on the ice in Northeast Greenland.[1] Inside the hut they drilled to a depth of 25 m with an auger similar to an oversized corkscrew.

Station Eismitte

Eismitte means Ice-Center in German, and the campsite was located 402 kilometers (250 miles) from the coast at an estimated altitude of 3,000 meters (9,843 feet).

As a member of the Alfred Wegener Expedition to Eismitte in central Greenland from July 1930 to August 1931, Ernst Sorge hand-dug a 15 m deep pit adjacent to his beneath-the-surface snow cave. Sorge was the first to systematically and quantitatively study the near-surface snow/firn strata from inside his pit. His research validated the feasibility of measuring the preserved annual snow accumulation cycles, like measuring frozen precipitation in a rain gauge.[2]

Camp VI

During 1950-1951 members of Expeditions Polaires Francaises (EPF) led by Paul Emile Victor reported boring two holes to depths of 126 and 150 m on the central Greenland inland ice at Camp VI and Station Central (Centrale).[3] Camp VI is in the western part of Greenland on the EPF-EGIG line at an elevation of 1598 masl.

Station Central

The Station Centrale was not far from station Eismitte.[1] Centrale is on a line between Milcent (70°18’N 45°35’W, 2410 masl) and Crête (71°7’N 37°19’W), at about (70°43'N 41°26'W), whereas Eismitte is at (71°10’N 39°56’W, ~3000 masl).

Site 2

In 1956, pre-International Geophysical Year (IGY) of 1957-58, a 10 cm diameter core using a rotary mechanical drill (US) to 305 m was recovered.[2]

A second 10 cm diameter core was recovered in 1957 by the same drill rig to 411 m. A commercially modified, mechanical-rotary Failing-1500 rock-coring rig was used, fitted with special ice cutting bits.[2]

Camp Century

Three cores were attempted at Camp Century in 1961, 1962, and again in 1963. The third hole was started in 1963 and reached 264 m. The 1963 hole was re-entered using the thermal drill (US) in 1964 and extended to 535 m. In mid-1965 the thermal drill was replaced with an electro-mechanical drill, 9.1 cm diameter, that reached the base of the ice sheet in July 1966 at 1387 m. The Camp Century, Greenland, (77°10’N 61°8’W, 1885 masl) ice core (cored from 1963-1966) is 1390 m deep and contains climatic oscillations with periods of 120, 940, and 13,000 years.[1]

Another core in 1977 was drilled at Camp Century using a Shallow (Dane) drill type, 7.6 cm diameter, to 100 m.

North Site

At the North Site (75°46’N 42°27’W, 2870 masl) drilling began in 1972 using a SIPRE (US) drill type, 7.6 cm diameter to 25 m. The North Site was 500 km north of the EGIG line. At a depth of 6-7 m diffusion had obliterated some of the seasonal cycles.[1]

North Central

The first core at North Central (74°37’N 39°36’W) was drilled in 1972 using a Shallow (Dane) drill type, 7.6 cm diameter to 100 m.

Crête

At Crête in central Greenland (71°7’N 37°19’W) drilling began in 1972 on the first core using a SIPRE (US) drill type, 7.6 cm diameter to 15 m.

The Crête core was drilled in central Greenland (1974) and reached a depth of 404.64 meters, extending back only about fifteen centuries.[4] Annual cycle counting showed that the oldest layer was deposited in 534 AD.[1]

The Crête 1984 ice cores consist of 8 short cores drilled in the 1984-85 field season as part of the post-GISP campaigns. Glaciological investigations were carried out in the field at eight core sites (A-H).[5]

Milcent

"The first core drilled at Station Milcent in central Greenland covers the past 780 years."[6] Milcent core was drilled at 70.3°N, 44.6°W, 2410 masl.[6] The Milcent core (398 m) was 12.4 cm in diameter, using a Thermal (US) drill type, in 1973.

Dye 2

Drilling with a Shallow (Swiss) drill type at Dye 2 (66°23’N 46°11’W, 2338 masl) began in 1973. The core was 7.6 cm in diameter to a depth of 50 m. A second core to 101 m was 10.2 cm in diameter was drilled in 1974. An additional core at Dye 2 was drilled in 1977 using a Shallow (US) drill type, 7.6 cm diameter, to 84 m.

Summit

The camp is located approximately 360 km from the east coast and 500 km from the west coast of Greenland at (Saattut, Uummannaq), and 200 km NNE of the historical ice sheet camp Eismitte. The closest town is Ittoqqortoormiit, 460 km ESE of the station. The station however is not part of Sermersooq municipality, but falls within the bounds of the Northeast Greenland National Park.

An initial core at Summit (71°17’N 37°56’W, 3212 masl) using a Shallow (Swiss) drill type was 7.6 cm in diameter for 31 m in 1974. Summit Camp, also Summit Station, is a year-round research station on the apex of the Greenland Ice Sheet. Its coordinates are variable, since the ice is moving. The coordinates provided here (72°34’45”N 38°27’26”W, 3212 masl) are as of 2006.

South Dome

The first core at South Dome (63°33’N 44°36’W, 2850 masl) used a Shallow (Swiss) drill type for a 7.6 cm diameter core to 80 m in 1975.

Hans Tausen (or Hans Tavsen)

The first GISP core drilled at Hans Tausen (82°30’N 38°20’W, 1270 masl) was in 1975 using a Shallow (Swiss) drill type, 7.6 cm diameter core to 60 m. The second core at Hans Tausen was drilled in 1976 using a Shallow (Dane) drill type, 7.6 cm diameter to 50 m. The drilling team reported that the drill was stuck in the drill hole and lost.

The Hans Tausen ice cap in Peary Land was drilled again with a new deep drill to 325 m. The ice core contained distinct melt layers all the way to bedrock indicating that Hans Tausen contains no ice from the glaciation; i.e., the world’s northernmost ice cap melted away during the post-glacial climatic optimum and was rebuilt when the climate got colder some 4000 years ago.[1]

Camp III

The first core at Camp III (69°43’N 50°8’W) was drilled in 1977 using a Shallow (Swiss) drill type, 7.6 cm, to 49 m. The last core at Camp III was drilled in 1978 using a Shallow (Swiss) drill type, 7.6 cm diameter, 80 m depth.

Dye 3

The Greenland Ice Sheet Project (GISP) including Dye 3 was a decade-long project to drill 20[7] ice cores in Greenland.

Renland

The Renland ice core was drilled in 1985.[1] The Renland ice core from East Greenland apparently covers a full glacial cycle from the Holocene into the previous Eemian interglacial. The Renland ice core is 325 m long.[8]

From the delta-profile, the Renland ice cap in the Scoresbysund Fiord has always been separated from the inland ice, yet all the delta-leaps revealed in the Camp Century 1963 core recurred in the Renland ice core.[1]

GRIP/GISP

See main articles: GRIP, GISP

The GRIP and GISP cores, each about 3000 m long, were drilled by European and US teams respectively on the summit of Greenland. Their usable record stretches back more than 100,000 years into the last interglacial. They agree (in the climatic history recovered) to a few metres above bedrock. However, the lowest portion of these cores cannot be interpreted, probably due to disturbed flow close to the bedrock.[27] There is evidence the GISP2 cores contain an increasing structural disturbance which casts suspicion on features lasting centuries or more in the bottom 10% of the ice sheet.[28] The more recent NorthGRIP ice core provides a undisturbed record to approx. 123,000 years before present. The results indicate that Holocene climate has been remarkably stable and have confirmed the occurrence of rapid climatic variation during the last ice age.

NGRIP

The NGRIP drilling site is near the center of Greenland (75°06′N 42°19′W / 75.1°N 42.32°W / 75.1; -42.32 (NGRIP drilling site), 2917 m, ice thickness 3085). Drilling began in 1999 and was completed at bedrock in 2003.[29] The NGRIP site was chosen to extract a long and undisturbed record stretching into the last glacial. NGRIP covers 5 kyr of the Eemian, and shows that temperatures then were roughly as stable as the pre-industrial Holocene temperatures were.

The North Greenland Eemian Ice Drilling (NEEM) site is located at 77°27’N 51°3.6’W, masl. Drilling started in June 2009 and expects to hit bedrock in 2010. The ice at NEEM may be 2545 m thick. As of Sep 1, 2009, the coring has reached a 1757.84 m depth for this season.

Antarctica

Vostok

Vostok team.

Up to as of 2003, the longest core drilled was at Vostok station. It reached back 420,000 years and revealed 4 past glacial cycles. Drilling stopped just above Lake Vostok. The Vostok core was not drilled at a summit, hence ice from deeper down has flowed from upslope; this slightly complicates dating and interpretation. Vostok core data are available.[30]

EPICA/Dome C

File:Epica do18 plot.png
The EPICA and Vostok cores compared

The EPICA core in Antarctica was drilled at 75°S 123°E / 75°S 123°E / -75; 123 (EPICA core) (560 km from Vostok) at an altitude of 3,233 m, near Dome C. The ice thickness is 3,309 +/-22 m and the core was drilled to 3,190 m. Present-day annual average air temperature is -54.5 °C and snow accumulation 25 mm/y. Information about the core was first published in Nature on June 10, 2004. The core went back 720,000 years and revealed 8 previous glacial cycles.

Dome F

Two deep ice cores were drilled near the Dome F summit (77°19′S 39°42′E / 77.317°S 39.700°E / -77.317; 39.700 (Dome F), altitude 3,810 m). The first drilling started in August 1995, reached a depth of 2503 m in December 1996 and covers a period back to 320,000 years. The second drilling started in 2003, was carried out during four subsequent austral summers from 2003/2004 until 2006/2007, and by then a depth of 3,035.22 m was reached. This core greatly extends the climatic record of the first core, and, according to a first, preliminary dating, it reaches back until 720,000 years.

WAIS Divide

The West Antarctice Ice Sheet Divide (WAIS Divide) Ice Core Drilling Project began drilling over the 2005 and 2006 seasons, drilling ice cores up to the depth of 300 m for the purposes of gas collection, other chemical applications, and to test the site for use with the Deep Ice Sheet Coring (DISC) Drill. Sampling with the DISC Drill will begin over the 2007 season and researchers and scientists expect that these new ice cores will provide data to establish a greenhouse gas record back over 40,000 years.

Non-polar cores

The non-polar ice caps, such as found on mountain tops, were traditionally ignored as serious places to drill ice cores because it was generally believed the ice would not be more than a few thousand years old, however since the 1970s ice has been found that is older, with clear chronological dating and climate signals going as far back as the beginning of the most recent ice age. Although polar cores have the clearest and longest chronological record, four-times or more as long, ice cores from tropical regions offer data and insights not available from polar cores and have been very influential in advancing understanding of the planets climate history and mechanisms.

Mountain ice cores have been retrieved in the Andes in South America, Mount Kilimanjaro in Africa, Tibet, various locations in the Himalayas, Alaska, Russia and elsewhere. Mountain ice cores are logistically very difficult to obtain. The drilling equipment must be carried by hand, organized as a mountaineering expedition with multiple stage camps, to altitudes upwards of 20,000 feet (helicopters are not safe), and the multi-ton ice cores must then be transported back down the mountain, all requiring mountaineering skills and equipment and logistics and working at low oxygen in extreme environments in remote third world countries. Scientists may stay at high altitude on the ice caps for up 20 to 50 days setting altitude endurance records that even professional climbers do not obtain. American scientist Lonnie Thompson has been pioneering this area since the 1970s, developing light-weight drilling equipment that can be carried by porters, solar-powered electricity, and a team of mountaineering-scientists. The ice core drilled in Guliya ice cap in western China in the 1990s reaches back to 760,000 years before the present — farther back than any other core at the time, though the EPICA core in Antarctica equalled that extreme in 2003.[31]

Because glaciers are retreating rapidly world-wide, some important glaciers are now no longer scientifically viable for taking cores, and many more glacier sites will continue to be lost, the "Snows of Mount Kilimanjaro" (Hemingway) for example could be gone by 2015. [32]

See also

Notes

  1. ^ a Kaspers, Karsten Adriaan. "Chemical and physical analyses of firn and firn air: from Dronning Maud Land, Antarctica; 2004-10-04". DAREnet. Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  2. ^ Bender M, Sowers T, Brook E (1997). "Gases in ice cores". Proc. Natl. Acad. Sci. U.S.A. 94 (16): 8343–9. doi:10.1073/pnas.94.16.8343. PMC 33751. PMID 11607743. {{cite journal}}: Unknown parameter |month= ignored (help)CS1 maint: multiple names: authors list (link)
  3. ^ "The Composition of Air in the Firn of Ice Sheets and the Reconstruction of Anthropogenic Changes in Atmospheric Chemistry". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  4. ^ "http://www.ssec.wisc.edu/icds/reports/Drill_Fluid.pdf" (PDF). Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); External link in |title= (help); Unknown parameter |dateformat= ignored (help)
  5. ^ "http://pubs.usgs.gov/prof/p1386j/history/history-lores.pdf" (PDF). Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); External link in |title= (help); Unknown parameter |dateformat= ignored (help)
  6. ^ "Journal of Geophysical Research (Oceans and Atmospheres) Special Issue [Full Text]". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  7. ^ "Physical Properties Research on the GISP2 Ice Core". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  8. ^ Svensson, A., S. W. Nielsen, S. Kipfstuhl, S. J. Johnsen, J. P. Steffensen, M. Bigler, U. Ruth, and R. Röthlisberger (2005). "Visual stratigraphy of the North Greenland Ice Core Project (NorthGRIP) ice core during the last glacial period". J. Geophys. Res. 110 (D02108): D02108. doi:10.1029/2004JD005134.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  9. ^ A.J. Gow and D.A. Meese. "The Physical and Structural Properties of the Siple Dome Ice Cores". WAISCORES. Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  10. ^ "Purdue study rethinks atmospheric chemistry from ground up". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  11. ^ "Summit_ACS.html". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  12. ^ Amy Ng and Clair Patterson (1981). "Natural concentrations of lead in ancient Arctic and Antarctic ice". Geochimica et Cosmochimica Acta. 45 (11): 2109–21. doi:10.1016/0016-7037(81)90064-8.
  13. ^ "Glacial ice cores: a model system for developing extraterrestrial decontamination protocols". Publications of Brent Christner. Retrieved May 23 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  14. ^ Michael Bender, Todd Sowersdagger, and Edward Brook (1997). "Gases in ice cores". Proc. Natl. Acad. Sci. USA. 94 (August): 8343–9. doi:10.1073/pnas.94.16.8343. PMID 11607743.{{cite journal}}: CS1 maint: multiple names: authors list (link) "Gases in ice cores". Proceedings of the National Academy of Sciences of the United States of America. Retrieved May 26 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  15. ^ "TRENDS: ATMOSPHERIC CARBON DIOXIDE". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  16. ^ "CMDL Annual Report 23: 5.6. MEASUREMENT OF AIR FROM SOUTH POLE FIRN". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  17. ^ "Climate Prediction Center — Expert Assessments". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  18. ^ M.M. Reddy, D.L. Naftz, P.F. Schuster. "FUTURE WORK". ICE-CORE EVIDENCE OF RAPID CLIMATE SHIFT DURING THE TERMINATION OF THE LITTLE ICE AGE. Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)CS1 maint: multiple names: authors list (link)
  19. ^ "Thermonuclear 36Cl". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  20. ^ Delmas RJ, J Beer, HA Synal; et al. (2004). "Bomb-test 36Cl measurements in Vostok snow (Antarctica) and the use of 36Cl as a dating tool for deep ice cores". Tellus B. 36 (5): 492. doi:10.1111/j.1600-0889.2004.00109.x. {{cite journal}}: Explicit use of et al. in: |author= (help)CS1 maint: multiple names: authors list (link)
  21. ^ Carpenter EJ, Lin S, Capone DG (2000). "Bacterial activity in South Pole snow". Appl. Environ. Microbiol. 66 (10): 4514–7. doi:10.1128/AEM.66.10.4514-4517.2000. PMC 92333. PMID 11010907. {{cite journal}}: Unknown parameter |month= ignored (help)CS1 maint: multiple names: authors list (link)
  22. ^ Warren SG, Hudson SR (2003). "Bacterial activity in South pole snow is questionable". Appl. Environ. Microbiol. 69 (10): 6340–1, author reply 6341. doi:10.1128/AEM.69.10.6340-6341.2003. PMC 201231. PMID 14532104. {{cite journal}}: Unknown parameter |month= ignored (help)
  23. ^ "Evidence for in-situ metabolic activity in ice sheets based on anomalous trace gas records from the Vostok and other ice cores". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  24. ^ "NOAA Paleoclimatology Program — Vostok Ice Core Timescales". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  25. ^ "Polar Paleo-Climate Interests". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  26. ^ Jim White and Eric Steig. "Siple Dome Highlights: Stable isotopes". WAISCORES. Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  27. ^ "GISP2 and GRIP Records Prior to 110 kyr BP". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  28. ^ Gow, A. J., D. A. Meese, R. B. Alley, J. J. Fitzpatrick, S. Anandakrishnan, G. A. Woods, and B. C. Elder (1997). "Physical and structural properties of the Greenland Ice Sheet Project 2 ice core: A review". J. Geophys. Res. 102 (C12): 26559–76. doi:10.1029/97JC00165.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  29. ^ Whitehouse, David (14 October 2005). "Breaking through Greenland's ice cap". BBC.
  30. ^ "NOAA Paleoclimatology Program — Vostok Ice Core". Retrieved October 14 2005. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |dateformat= ignored (help)
  31. ^ Bowen, Mark (2005). Thin Ice. Henry Holt Company, ISBN 0-8050-6443-5

References

  • http://www.tonderai.co.uk/earth/ice_cores.php "The Chemistry of Ice Cores" literature review
  • Barnola J, Pimienta P, Raynaud D, Korotkevich Y (1991). "CO2-Climate relationship as deduced from the Vostok ice core – a reexamination based on new measurements and on a reevaluation of the air dating". Tellus Series B-Chemical and Physical Meteorology. 43 (2): 83–90. doi:10.1034/j.1600-0889.1991.t01-1-00002.x.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  • Battle M, Bender M, Sowers T; et al. (1996). "Atmospheric gas concentrations over the past century measured in air from firn at the South Pole". Nature. 383 (6597): 231–5. doi:10.1038/383231a0. {{cite journal}}: Explicit use of et al. in: |author= (help)CS1 maint: multiple names: authors list (link)
  • Friedli H, Lotscher H, Oeschger H; et al. (1986). "Ice core record of the C13/C12 ratio of atmospheric CO2 in the past 2 centuries". Nature. 324 (6094): 237–8. doi:10.1038/324237a0. {{cite journal}}: Explicit use of et al. in: |author= (help)CS1 maint: multiple names: authors list (link)
  • NGRIP project members, Nature 9 September 2004: High resolution record of Northern Hemisphere climate extending into the last interglacial period.
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  2. ^ a b c Langway CC Jr. (2008). "The History of Early Polar Ice Cores" (PDF). {{cite web}}: Unknown parameter |month= ignored (help) Cite error: The named reference "Langway" was defined multiple times with different content (see the help page).
  3. ^ Wegener K (1955). "Die temperatur in Grönlandischen inlandeis". Pure Appl Geophys. 32 (1): 102–6. doi:10.1007/BF01993599. {{cite journal}}: Unknown parameter |month= ignored (help)
  4. ^ Rose LE. "The Greenland Ice Cores". Kronos. 12 (1): 55–68. {{cite journal}}: Unknown parameter |month= ignored (help)
  5. ^ "Crete Ice Core".
  6. ^ a b Oeschger H, Beer J, Andree M (1987). "10Be and 14C in the Earth system". Phil Trans R Soc Lond A. 323 (1569): 45–56. {{cite journal}}: Unknown parameter |month= ignored (help)CS1 maint: multiple names: authors list (link)
  7. ^ "NOAA Paleoclimatology World Data Centers Dye 3 Ice Core".
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